Onsistent with a solvent-exposed carbamate that is not involved in an intramolecular H-bond. A number of long-range NOEs are observed in the NOESY spectrum of 7, including Boc(Dmaa) (Gly), NH(Dmaa) NH(Gly), Boc(Dmaa) (Acpc), and NH(Gly) (D-Pro) correlations (Figure S5.03). Much like peptides 3 and 16, a strong NH(Acpc) (D-Pro) NOE provides evidence for type II loop dihedrals, although the mod